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Canonical partition functions: ideal quantum gases, interacting classical gases, and interacting quantum gases

机译:规范分配功能:理想的量子气体,相互作用   经典气体和相互作用的量子气体

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摘要

In statistical mechanics, for a system with fixed number of particles, e.g.,a finite-size system, strictly speaking, the thermodynamic quantity needs to becalculated in the canonical ensemble. Nevertheless, the calculation of thecanonical partition function is difficult; even the canonical partitionfunction of ideal Bose and Fermi gases cannot be obtained exactly. In thispaper, based on the mathematical theory of the symmetric function and the Bellpolynomial, we suggest a method for the calculation of the canonical partitionfunction of ideal quantum gases, including ideal Bose, Fermi, and Gentilegases. Moreover, we also reveal that the canonical partition functions ofinteracting classical and quantum gases given by the classical and quantumcluster expansion methods are indeed the Bell polynomial in mathematics. Thevirial coefficients of ideal Bose, Fermi, and Gentile gases is calculated fromthe exact canonical partition function. The virial coefficients of interactingclassical and quantum gases is calculated from the canonical partition functionby using the expansion of the Bell polynomial, rather than calculated from thegrand canonical potential.
机译:在统计力学中,严格来说,对于具有固定数量的粒子的系统(例如,有限大小的系统),需要在规范集合中计算热力学量。然而,规范划分函数的计算是困难的。即使理想的玻色和费米气体的规范分配函数也无法精确获得。在本文中,基于对称函数和Bell多项式的数学理论,我们提出了一种计算理想量子气体(包括理想Bose,Fermi和Gentilegas)的规范分配函数的方法。此外,我们还揭示了经典和量子簇展开方法给出的与经典和量子气体相互作用的规范分配函数的确是数学中的贝尔多项式。理想的Bose,Fermi和Gentile气体的病毒系数由确切的规范分配函数计算得出。相互作用的经典气体和量子气体的病毒系数是通过使用Bell多项式的展开从规范分配函数计算的,而不是从正典势计算的。

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